Dissolution of Platinum: Limits for the Deployment of Electrochemical Energy Conversion?**
نویسندگان
چکیده
Platinum stability: Dissolution of Pt, which is one major degradation mechanism in, for example, hydrogen/air fuel cells, was monitored under potentiodynamic and potentiostatic conditions. The highly sensitive and time-resolving dissolution monitoring enables the distinction between anodic and cathodic dissolution processes during potential transient and chronoamperometric experiments, and the precise quantification of the amount of dissolved Pt.
منابع مشابه
Platinum Extraction Modeling from Used Catalyst by Iodine Solutions
Platinum extraction from spent reforming catalysts in iodine solutions under atmospheric pressure at different temperatures, acid concentration, and iodine spices concentration, catalyst particle size, and impeller agitation speed have been studied in our group. In this system, platinum is oxidized from spent catalyst with I3¯ that is formed ...
متن کاملA NEW GAS DIFFUSION ELECTRODE (GDE) WITH A BETTER O2 REDUCTION ELECTROCATALYSTS WITH VERY LOW PT CONTENTS VIA NANO-SIZED PT-COATED NAFION
In the present study, a new gas diffusion electrode (GDE) (based on Pt/Nafion membrane) is fabricated. The electrochemical results show that the new GDE has the highest electrochemical activity toward the oxygen reduction reaction (ORR) among the three electrodes. The SEM and XRD findings show that a platinum layer can be attached to Nafion membrane closely and firmly with a strong peak corresp...
متن کاملSeparation and Recovery of Platinum and Palladium from Spent Petrochemical Catalysts Using Activated Carbon, Analysis of Two Kind of Most Used Catalysts in Petro Chemistry
The goal of this work is the separation and recovery of platinum and palladium from spent catalyst. The recovery consisted of separating the maximum amount of platinum and palladium from catalysts and changing them into usable forms. The petroleum and petrochemical units use Pt and Pd catalyst for reactions such as reforming and hydrogenation. Because these materials contain valuable metals...
متن کاملElectrodeposition of platinum nanoparticles on reduced graphene oxide as an efficient catalyst for oxygen reduction reaction
Reduced graphene oxide film was synthesized on a glassy carbon electrode by electro reduction of graphene oxide powders in aqueous solution. Then platinum nano particles were deposited on reduced graphene oxide film that was deposited on the glassy carbon electrode via electro reduction of platinum salt. The Physical morphology of the platinum on reduced graphene oxide film was evaluated by sca...
متن کاملThe investigation of pyrocatechol electrochemical mechanism in presence of nitrite ion on platinum electrode
In this study, the electrochemical mechanism of catechol in presence and absence of nitrite ion, is investigated in phosphate buffer medium (pH=7) using platinum electrode through cyclic voltammetry method in various scan rates. Electrochemical oxidation of catechol showed how quinone has changed to o-benzoquinone and also how o-benzoquinone has reacted with nitrite ion and potential scan rate ...
متن کامل